The preparation of some manganese–mercury cluster complexes and a study of their redistribution reactions
Iggo, Jonathan A.; Mays, Martin J.
Журнал:
Journal of the Chemical Society, Dalton Transactions
Дата:
1984
Аннотация:
The heterometallic cluster complexes [Mn2(µ-HgPh)(µ-PPh2)(CO)8](2), [Mn2(µ-HgCl)(µ-PPh2)(CO)8](3), and [Hg{Mn2(µ-PPh2)(CO)8}2](4) have been prepared by reaction of [N(PPh3)2][Mn2(µ-PPh2)(CO)8](1) with, respectively, HgPhCl, HgCl2, and Hg(CN)2. Some redistribution reactions of (2), (3), and (4)(in which the Hg atom is three- or four-co-ordinate) have been investigated and are compared with previously studied redistribution reactions of transition-metalâ mercury complexes containing two-co-ordinate mercury atoms.
408.0Кб