Low-temperature magnetic resonance studies on oxygen fluorides
Lawrence, N. J.; Ogden, J. S.; Turner, J. J.
Журнал:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical
Дата:
1968
Аннотация:
The <sup>19</sup>F chemical shift of dioxygen difluoride (O2F2) was measured and its dependence on the concentration of the O2F radical present in the experiments was shown to be negligible. Photolysis of liquid OF2â O2 mixtures produces deep red solutions which show electron-spin resonance signals of very great intensity due to O2F; possible mechanisms for the formation of the free radical are briefly discussed.
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